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Comportamento de fases e morfologia de misturas de polÃmeros sob elevadas taxas de fluxo
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ISBN10: 6630061659
ISBN13: 9786630061659
Publisher: Edicoes Nosso Conhecimento
Published: May 18 2026
Pages: 164
Weight: 0.50
Height: 0.38 Width: 6.00 Depth: 9.00
Language: Portuguese
ISBN13: 9786630061659
Publisher: Edicoes Nosso Conhecimento
Published: May 18 2026
Pages: 164
Weight: 0.50
Height: 0.38 Width: 6.00 Depth: 9.00
Language: Portuguese
O efeito do fluxo reveste-se de relevância industrial na extrusão por fusão e na moldagem por injeção, onde se verificam gradientes de temperatura e elevadas taxas de deformação. Isto exige uma melhor compreensão da dependência do comportamento das fases em relação ao fluxo nas misturas de polÃmeros, uma vez que a morfologia e as propriedades do produto final são influenciadas em grande medida pelos detalhes da dinâmica da massa fundida em fluxo. Experimentalmente, foram observados fenómenos de mistura induzida por cisalhamento e de desmistura induzida por cisalhamento sob uma variedade de condições operacionais. O objetivo principal deste livro é explicar o comportamento de fase sob taxas de deformação realisticamente industriais, utilizando uma mistura parcialmente miscÃvel de SAN/PMMA como exemplo, e esclarecer o efeito do fluxo de cisalhamento na morfologia da amostra moldada por injeção. O leitor aprenderá resumidamente a termodinâmica básica da separação de fases, a termodinâmica das misturas de polÃmeros e como detetar a miscibilidade dos polÃmeros utilizando a espectroscopia Raman e outras técnicas. O efeito do fluxo de cisalhamento no comportamento de fase da mistura de polÃmeros é demonstrado teoricamente e experimentalmente.
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