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Phasenverhalten und Morphologie von Polymermischungen bei hohen Fließgeschwindigkeiten
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ISBN10: 6630046293
ISBN13: 9786630046298
Publisher: Verlag Unser Wissen
Published: May 18 2026
Pages: 164
Weight: 0.50
Height: 0.38 Width: 6.00 Depth: 9.00
Language: German
ISBN13: 9786630046298
Publisher: Verlag Unser Wissen
Published: May 18 2026
Pages: 164
Weight: 0.50
Height: 0.38 Width: 6.00 Depth: 9.00
Language: German
Der Einfluss der Strömung ist in der Schmelzextrusion und im Spritzgie en von industrieller Bedeutung, wo Temperaturgradienten und hohe Verformungsraten auftreten. Dies erfordert ein besseres Verständnis der Strömungsabhängigkeit des Phasenverhaltens in Polymermischungen, da die Morphologie und die Eigenschaften des Endprodukts in hohem Ma e von den Details der Dynamik der strömenden Schmelze beeinflusst werden. Experimentell wurden unter verschiedenen Betriebsbedingungen sowohl scherinduzierte Vermischungs- als auch scherinduzierte Entmischungsphänomene beobachtet. Das Hauptziel dieses Buches ist es, das Phasenverhalten unter industriell realistischen Verformungsraten am Beispiel einer teilweise mischbaren SAN/PMMA-Mischung zu erläutern und den Einfluss der Scherströmung auf die Morphologie der spritzgegossenen Probe zu verdeutlichen. Der Leser erhält einen kurzen Überblick über die grundlegende Thermodynamik der Phasentrennung, die Thermodynamik von Polymermischungen und die Methoden zur Bestimmung der Mischbarkeit von Polymeren mittels Ramanspektroskopie und anderer Techniken. Der Einfluss der Scherströmung auf das Phasenverhalten von Polymermischungen wird theoretisch und experimentell aufgezeigt.
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