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Comportamento di fase e morfologia delle miscele polimeriche in condizioni di elevata velocità di scorrimento
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ISBN10: 6630059093
ISBN13: 9786630059090
Publisher: Edizioni Sapienza
Published: May 18 2026
Pages: 160
Weight: 0.49
Height: 0.37 Width: 6.00 Depth: 9.00
Language: Italian
ISBN13: 9786630059090
Publisher: Edizioni Sapienza
Published: May 18 2026
Pages: 160
Weight: 0.49
Height: 0.37 Width: 6.00 Depth: 9.00
Language: Italian
L'effetto dello scorrimento riveste rilevanza industriale nell'estrusione a fusione e nello stampaggio a iniezione, dove si riscontrano gradienti di temperatura ed elevate velocità di deformazione. Ciò richiede una migliore comprensione della dipendenza dal flusso del comportamento di fase nelle miscele polimeriche, poiché la morfologia e le proprietà del prodotto finito sono influenzate in larga misura dai dettagli della dinamica della massa fusa in movimento. Sperimentalmente, sono stati osservati sia fenomeni di miscelazione indotti dal taglio che fenomeni di separazione indotti dal taglio in una varietà di condizioni operative. L'obiettivo principale di questo libro è spiegare il comportamento di fase a velocità di deformazione realistiche dal punto di vista industriale utilizzando come esempio una miscela parzialmente miscibile di SAN/PMMA e chiarire l'effetto del flusso di taglio sulla morfologia del campione stampato a iniezione. Il lettore apprenderà brevemente i fondamenti della termodinamica della separazione di fase, della termodinamica delle miscele polimeriche e di come rilevare la miscibilità dei polimeri utilizzando la spettroscopia Raman e altre tecniche. L'effetto del flusso di taglio sul comportamento di fase della miscela polimerica viene dimostrato teoricamente e sperimentalmente.
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