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Aplicação da Calorimetria de Velocidade Acelerada em Células de Iões de LÃtio
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ISBN10: 620869356X
ISBN13: 9786208693565
Publisher: Edicoes Nosso Conhecimento
Published: Feb 26 2025
Pages: 88
Weight: 0.28
Height: 0.21 Width: 6.00 Depth: 9.00
Language: Portuguese
ISBN13: 9786208693565
Publisher: Edicoes Nosso Conhecimento
Published: Feb 26 2025
Pages: 88
Weight: 0.28
Height: 0.21 Width: 6.00 Depth: 9.00
Language: Portuguese
Os aditivos para electrólitos podem prolongar o tempo de vida das células de iões de lÃtio porque podem modificar a interfase electrolÃtica sólida (SEI) no elétrodo negativo e a camada de passivação no elétrodo positivo. Os aditivos electrolÃticos afectam as reacções entre os eléctrodos carregados e os electrólitos a alta temperatura e podem ter impacto na segurança das células de iões de lÃtio. A fim de poder distinguir os efeitos de um aditivo ou de misturas de aditivos na reatividade dos eléctrodos positivos ou negativos com os electrólitos a temperaturas elevadas, foi desenvolvido um método experimental baseado na calorimetria de velocidade acelerada (ARC). Este método provou ser útil e mostrou que os aditivos selecionados afectavam mais a reação entre a grafite litiada e os electrólitos do que a reação entre o Li(Ni1/3Mn1/3Co1/3)O2 delitizado e os electrólitos. Alguns dos aditivos selecionados ou combinações de aditivos diminuÃram drasticamente a taxa de auto-aquecimento em comparação com o eletrólito de controlo. A incorporação desses aditivos ou combinações de aditivos nas células de iões de lÃtio deverá conduzir a células de iões de lÃtio mais seguras.
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