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L'applicazione della calorimetria adiabatica di rateazione nelle celle agli ioni di litio
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ISBN10: 6208693527
ISBN13: 9786208693527
Publisher: Edizioni Sapienza
Published: Feb 26 2025
Pages: 84
Weight: 0.27
Height: 0.20 Width: 6.00 Depth: 9.00
Language: Italian
ISBN13: 9786208693527
Publisher: Edizioni Sapienza
Published: Feb 26 2025
Pages: 84
Weight: 0.27
Height: 0.20 Width: 6.00 Depth: 9.00
Language: Italian
Gli additivi per elettroliti possono prolungare la durata delle celle agli ioni di litio perché possono modificare l'interfaccia dell'elettrolita solido (SEI) sull'elettrodo negativo e lo strato di passivazione sull'elettrodo positivo. Gli additivi per elettroliti influenzano le reazioni tra gli elettrodi caricati e gli elettroliti ad alta temperatura e possono influire sulla sicurezza delle celle agli ioni di litio. Per poter distinguere gli effetti di un additivo o di miscele di additivi sulla reattività degli elettrodi positivi o negativi con elettroliti a temperature elevate, è stato sviluppato un metodo sperimentale basato sulla calorimetria ad accelerazione di velocità (ARC). Questo metodo si è dimostrato utile e ha mostrato che gli additivi selezionati influenzavano la reazione tra grafite litata ed elettroliti più di quella tra Li(Ni1/3Mn1/3Co1/3)O2 delithiated ed elettroliti. Alcuni degli additivi selezionati o combinazioni di additivi hanno ridotto drasticamente il tasso di autoriscaldamento rispetto all'elettrolita di controllo. L'incorporazione di tali additivi o combinazioni di additivi nelle celle agli ioni di litio dovrebbe portare a celle agli ioni di litio più sicure.
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