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Zastosowanie kalorymetrii przyspieszającej w ogniwach litowo-jonowych
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ISBN10: 6208693535
ISBN13: 9786208693534
Publisher: Wydawnictwo Nasza Wiedza
Published: Feb 26 2025
Pages: 88
Weight: 0.28
Height: 0.21 Width: 6.00 Depth: 9.00
Language: Polish
ISBN13: 9786208693534
Publisher: Wydawnictwo Nasza Wiedza
Published: Feb 26 2025
Pages: 88
Weight: 0.28
Height: 0.21 Width: 6.00 Depth: 9.00
Language: Polish
Dodatki do elektrolitu mogą wydlużyc żywotnośc ogniw litowo-jonowych, ponieważ mogą modyfikowac stalą interfazę elektrolitu (SEI) na elektrodzie ujemnej i warstwę pasywacyjną na elektrodzie dodatniej. Dodatki do elektrolitów wplywają na reakcje między naladowanymi elektrodami i elektrolitami w wysokiej temperaturze i mogą wplywac na bezpieczeństwo ogniw litowo-jonowych. Aby móc rozróżnic wplyw dodatku lub mieszanek dodatków na reaktywnośc elektrod dodatnich lub ujemnych z elektrolitami w podwyższonych temperaturach, opracowano metodę eksperymentalną opartą na kalorymetrii przyspieszonej (ARC). Metoda ta okazala się przydatna i wykazala, że wybrane dodatki mialy większy wplyw na reakcję litowanego grafitu z elektrolitem niż na reakcję litowanego Li(Ni1/3Mn1/3Co1/3)O2 z elektrolitem. Niektóre z wybranych dodatków lub kombinacji dodatków znacznie zmniejszyly szybkośc samonagrzewania w porównaniu z elektrolitem kontrolnym. Wlączenie takich dodatków lub kombinacji dodatków do ogniw litowo-jonowych powinno prowadzic do bezpieczniejszych ogniw litowo-jonowych.
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