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Selektywne katalityczne utlenianie amoniaku do azotu i pary wodnej
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ISBN10: 6630243307
ISBN13: 9786630243307
Publisher: Wydawnictwo Nasza Wiedza
Published: Jul 2 2026
Pages: 64
Weight: 0.22
Height: 0.15 Width: 6.00 Depth: 9.00
Language: Polish
ISBN13: 9786630243307
Publisher: Wydawnictwo Nasza Wiedza
Published: Jul 2 2026
Pages: 64
Weight: 0.22
Height: 0.15 Width: 6.00 Depth: 9.00
Language: Polish
Rosnąca ilośc amoniaku przedostającego się do atmosfery ma negatywny wplyw na technologie DeNOx stosowane w celu redukcji emisji tlenków azotu z elektrowni i innych stacjonarnych źródel emisji NOx, a także z ciężarówek oraz samochodów osobowych z silnikami benzynowymi i wysokoprężnymi. Konieczne jest kontrolowanie i usuwanie emisji amoniaku ze strumieni odpadowych. Proces selektywnego katalitycznego utleniania amoniaku do azotu i pary wodnej jest jedną z najbardziej obiecujących metod eliminacji toksycznego amoniaku ze spalin. Jako katalizatory w tym procesie przetestowano mieszane tlenki metali pochodzące z hydrotalcytu. Wyniki badań przeprowadzonych w ramach tego projektu zostaly przedstawione w czterech artykulach naukowych (Catalysis Letters, Applied Catalysis B: Environmental, Journal of Thermal Analysis and Calorimetry, Chemik). Stwierdzono, że mieszane tlenki metali wykazują aktywnośc, selektywnośc względem azotu oraz stabilnośc w procesie utleniania amoniaku. Ich aktywnośc i selektywnośc silnie zależą od skladu chemicznego i fazowego oraz wlaściwości redoks. Zaproponowano optymalny sklad katalizatorów gwarantujący wysoką wydajnośc katalityczną. Zbadano mechanizm wewnętrznego SCR (i-SCR) dla reakcji zachodzącej na badanych katalizatorach.
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