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Selektive katalytische Oxidation von Ammoniak zu Stickstoff und Wasserdampf
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ISBN10: 6630245865
ISBN13: 9786630245868
Publisher: Verlag Unser Wissen
Published: Jul 2 2026
Pages: 64
Weight: 0.22
Height: 0.15 Width: 6.00 Depth: 9.00
Language: German
ISBN13: 9786630245868
Publisher: Verlag Unser Wissen
Published: Jul 2 2026
Pages: 64
Weight: 0.22
Height: 0.15 Width: 6.00 Depth: 9.00
Language: German
Ein zunehmender Ammoniakaustritt beeinträchtigt die DeNOx-Technologie, die zur Reduzierung der Stickoxidemissionen aus Kraftwerken und anderen stationären NOx-Emissionsquellen sowie aus schweren Lkw und Benzin- und Diesel-Pkw eingesetzt wird. Die Kontrolle und Beseitigung von Ammoniakemissionen in Abgasströmen ist daher erforderlich. Der Prozess der selektiven katalytischen Oxidation von Ammoniak zu Stickstoff und Wasserdampf ist eine der vielversprechendsten Methoden zur Beseitigung von giftigem Ammoniak aus Rauchgasen. Als Katalysatoren für diesen Prozess wurden aus Hydrotalcit gewonnene Mischmetalloxide getestet. Die im Rahmen der Forschung durchgeführten Untersuchungen wurden in vier wissenschaftlichen Artikeln vorgestellt (Catalysis Letters, Applied Catalysis B: Environmental, Journal of Thermal Analysis and Calorimetry, Chemik). Es wurde festgestellt, dass Mischmetalloxide bei der Ammoniakoxidation aktiv, selektiv gegenüber Stickstoff und stabil sind. Ihre Aktivität und Selektivität hängen stark von der chemischen und phasenbezogenen Zusammensetzung sowie von ihren Redox-Eigenschaften ab. Es wurde eine optimale Zusammensetzung der Katalysatoren vorgeschlagen, die eine hohe katalytische Leistung gewährleistet. Der interne SCR-Mechanismus (i-SCR) wurde für die auf den untersuchten Katalysatoren ablaufende Reaktion untersucht.
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