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Supercritical Fluids: Fundamentals for Application

Supercritical Fluids: Fundamentals for Application

Hardcover

Series: NATO Science Series E:, Book 273

Technology & EngineeringChemistry

ISBN10: 0792329422
ISBN13: 9780792329428
Publisher: Springer Nature
Published: Jun 30 1994
Pages: 796
Weight: 2.89
Height: 1.69 Width: 6.14 Depth: 9.21
Language: English
Supercritical fluids which are neither gas nor liquid, but can be compressed gradually from low to high density, are gaining increasing importance as tunable solvents and reaction media in the chemical process industry. By adjusting the pressure, or more strictly the density, the properties of these fluids are customized and manipulated for the particular process at hand, be it a physical transformation, such as separation or solvation, or a chemical transformation, such as a reaction or reactive extraction. Supercritical fluids, however, differ from both gases and liquids in many respects. In order to properly understand and describe their properties, it is necessary to know the implications of their nearness to criticality, to be aware of the complex types of phase separation (including solid phases) that occur when the components of the fluid mixture are very different from each other, and to develop theories that can cope with the large differences in molecular size and shape of the supercritical solvent and the solutes that are present.

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