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Badanie interkalacji litu w dwufazowym FeNbO₄
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ISBN10: 6208896479
ISBN13: 9786208896478
Publisher: Wydawnictwo Nasza Wiedza
Published: Jul 16 2025
Pages: 52
Weight: 0.18
Height: 0.12 Width: 6.00 Depth: 9.00
Language: Polish
ISBN13: 9786208896478
Publisher: Wydawnictwo Nasza Wiedza
Published: Jul 16 2025
Pages: 52
Weight: 0.18
Height: 0.12 Width: 6.00 Depth: 9.00
Language: Polish
Materialy nanostrukturalne są znacznie bardziej efektywne niż materialy masowe, gdy są stosowane jako elektrody w akumulatorach litowo-jonowych. Wynika to z faktu, że ich mniejszy rozmiar pozwala jonom litu poruszac się szybciej i latwiej, poprawiając szybkośc ladowania i rozladowywania. Lepiej radzą sobie również z naprężeniami powodowanymi przez lit wchodzący i wychodzący z materialu. Gdy rozmiar cząstek zostanie zmniejszony do zaledwie kilku nanometrów, sposób, w jaki lit reaguje z materialem, może się znacznie zmienic. Na przyklad FeNbO4 o strukturze α-PbO2 zachowuje się bardzo różnie w zależności od wielkości cząstek. W badaniu FeNbO4 wykonano zarówno w rozmiarach nanometrowych, jak i mikrometrowych przy użyciu metod zol-żel (SG) i reakcji w stanie stalym (SSR). Spośród dwóch badanych struktur krystalicznych - α-PbO2 i wolframitu - forma α-PbO2 wykazala lepszą retencję pojemności.
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