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In-Situ Structure Characterization of Elastomers During Deformation and Fracture

In-Situ Structure Characterization of Elastomers During Deformation and Fracture

Hardcover

Series: Springer Theses

Technology & EngineeringPhysics

ISBN10: 3319069063
ISBN13: 9783319069067
Publisher: Springer Nature
Published: Jul 8 2014
Pages: 124
Weight: 0.83
Height: 0.38 Width: 6.14 Depth: 9.21
Language: English

This thesis offers novel insights into the time-dependent structural evolution of polymers under deformation. In-situ tensile experiments at high-brilliance synchrotron sources allowed to characterize the material with unrivaled resolution in time and space. The strain-induced crystallization in natural rubber was studied by wide-angle X-ray diffraction. Special emphasis was put on the establishment of new structure-property relationships to give a more in-depth understanding of the mechanical performance of rubber parts, e.g. in tear fatigue loading. To this end, the kinetics of strain-induced crystallization were investigated, subjecting the material to high strain rates. The local structure around a crack tip was observed by scanning wide-angle X-ray diffraction. Ultra-small angle X-ray scattering served to study filled elastomers under deformation, from specially prepared model filler systems to industrially relevant carbon black filled rubbers. Other methods include electron microscopy coupled with in-situ tensile testing and optical dilatometry to examine cavitation in rubbers.

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