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Enantioselective Electrochemical C-H Activation Enabled by Sustainable 3D Transition Metal Catalysis
Paperback
Series: Bestmasters
ISBN13: 9783658471095
Publisher: Springer Spektrum
Published: Feb 22 2025
Pages: 96
Weight: 0.30
Height: 0.26 Width: 5.83 Depth: 8.27
Language: English
Enantioselective metallaelectro-catalyzed C─H activation represents an innovative strategy for enabling the transition of organic synthesis to a more resource-economic mode of operation. It circumvents substrate prefunctionalization by directly exploiting otherwise inert C─H bonds to construct complex three-dimensional scaffolds from simple molecular building blocks. Furthermore, the mild electrocatalytic conditions evade chemical oxidants, while producing molecular hydrogen as the sole by-product, enabling the connection of organic synthesis to a possible future decentralized green hydrogen economy.
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