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Crystallization and Growth of Colloidal Nanocrystals

Crystallization and Growth of Colloidal Nanocrystals

Paperback

Series: Springerbriefs in Materials

Technology & EngineeringChemistry

ISBN10: 1461413079
ISBN13: 9781461413073
Publisher: Springer Nature
Published: Dec 6 2011
Pages: 95
Weight: 0.35
Height: 0.30 Width: 6.00 Depth: 8.90
Language: English

Since the size, shape, and microstructure of nanocrystalline materials strongly impact physical and chemical properties, the development of new synthetic routes to nanocrystals with controlled composition and morphology is a key objective of the nanomaterials community. This objective is dependent on control of the nucleation and growth mechanisms that occur during the synthetic process, which in turn requires a fundamental understanding of both classical nucleation and growth and non-classical growth processes in nanostructured materials. Recently, a novel growth process called Oriented Attachment (OA) was identified which appears to be a fundamental mechanism during the development of nanoscale materials. OA is a special case of aggregation that provides an important route by which nanocrystals grow, defects are formed, and unique--often symmetry-defying--crystal morphologies can be produced. This growth mechanism involves reversible self-assembly of primary nanocrystals followed by reorientation of the assembled nanoparticles to achieve structural accord at the particle-particle interface, the removal of adsorbates and solvent molecules, and, finally, the irreversible formation of chemical bonds to produce new single crystals, twins, and intergrowths.

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