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Synthesis and Structural Characterization of Arsinoamide and its Metal Complexes

Synthesis and Structural Characterization of Arsinoamide and its Metal Complexes

Paperback

Chemistry

ISBN10: 373697034X
ISBN13: 9783736970342
Publisher: Cuvillier
Published: Jun 20 2019
Pages: 138
Weight: 0.38
Height: 0.30 Width: 5.83 Depth: 8.27
Language: English
The phosphinoamide chemistry has attracted a considerable attention owing to the structural diversity of the associated complexes. To further understand the properties of the P-N bond, Ashby synthesized the compound [(Ph2P-NPh)Li(Et2O)] through the deprotonation reaction of the corresponding aminophosphine with nBuLi. X-ray diffraction analyses indicated the presence of Li-P bonds (2.684 and 3.004 Ã…). In addition, the P-N bond length (1.672(2) Ã…) was relatively smaller than that of a single bond (mean value of 1.70).

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Chemistry