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Organic Solid-State Reactions

Organic Solid-State Reactions

Hardcover

ChemistryPhysics

ISBN10: 1402002270
ISBN13: 9781402002274
Publisher: Springer
Published: Apr 30 2002
Pages: 275
Weight: 1.30
Height: 0.76 Width: 6.42 Depth: 9.76
Language: English

Most organic reactions have long been carried out in organic solvents without concern for their real necessity, reaction efficiency, and pollution problems. Very recently, we have found that most organic reactions can be carried out in the absence of a solvent, namely, in the solid state. In many cases, the solid-state reaction proceeds more easily and efficiently, and even more selectively than solution reaction. This shows that molecules move easily and selectively in the solid state. This finding changed the classical idea which suggests molecules do not move and reactions do not occur in the solid state, and opened up a new research field for the study molecular dynamics in the solid state. The organic solid state reactions have many possibilities to be developed. For example, enantioselective reactions can easily be accomplished by carrying out the reaction in an inclusion complex crystal with an optically active host compound.

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