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Nickelgruppe: Elemente Der Zehnten Nebengruppe: Eine Reise Durch Das Periodensystem
Paperback
Series: Essentials
Publisher Price: $17.99
ISBN13: 9783658168070
Publisher: Springer Spektrum
Published: Mar 10 2017
Pages: 46
Weight: 0.18
Height: 0.12 Width: 5.83 Depth: 8.27
Language: German
Hermann Sicius stellt ausführlich die Elemente der zehnten Nebengruppe (Nickel, Palladium, Platin und Darmstadtium) vor, deren physikalische und chemische Eigenschaften relativ ähnlich sind. Nickel wurde 1751 entdeckt, Palladium 1803, und Platin war zumindest in legierter Form schon in Altägypten bekannt. Auch beim Elementenpaar Palladium und Platin erkennt man noch die Auswirkung der Lanthanoidenkontraktion. Die jeweiligen physikalischen Eigenschaften dieser zwei Elemente unterscheiden sich jedoch schon merklich, nicht aber die chemischen. Die Eigenschaften des Nickels dagegen weichen von denen der zwei edlen Platinmetalle Palladium und Platin deutlich ab. So zeigt Nickel ein negatives Normalpotential sowie niedrigere Dichten, Schmelz- und Siedepunkte. Bei Nickel ist die Oxidationsstufe +2 die stabilste, Palladium und Platin treten jeweils mit der Oxidationsstufe +2 und +4 auf und Iridium mit +4. 1994 konnten die ersten Atome des Darmstadtiums erzeugt werden.
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