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Diradicaloids

Diradicaloids

Hardcover

ChemistryGeneral Science

Currently unavailable to order

ISBN10: 9814968080
ISBN13: 9789814968089
Publisher: Jenny Stanford Pub
Published: Apr 1 2022
Pages: 622
Language: English

π-Conjugated molecules with an even number of π-electrons usually have a closed-shell ground state. However, recent studies have demonstrated that a certain type of molecules could show open-shell singlet ground state and display diradical-like (diradicaloid) behavior. Their electronic structure can be understood in terms of the diradical character and aromaticity concepts. They display very different electronic properties from traditional closed-shell π-conjugated molecules and could be used as next-generation molecular materials.

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