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  • Open Daily: 10am - 10pm
    Alley-side Pickup: 10am - 7pm

    3038 Hennepin Ave Minneapolis, MN
    612-822-4611

Open Daily: 10am - 10pm | Alley-side Pickup: 10am - 7pm
3038 Hennepin Ave Minneapolis, MN
612-822-4611
Development of Synthetic Methods for Novel Photofunctional Multinuclear Complexes: Simple Synthetic Methods for Multinuclear Complexes Using Various C

Development of Synthetic Methods for Novel Photofunctional Multinuclear Complexes: Simple Synthetic Methods for Multinuclear Complexes Using Various C

Yamazaki, Yasuomi

Paperback

Series: Springer Theses

Chemistry

ISBN10: 9811671508
ISBN13: 9789811671500
Publisher: Springer Nature
Published: Nov 14 2022
Pages: 105
Weight: 0.39
Height: 0.25 Width: 6.14 Depth: 9.21
Language: English

This book presents several helpful synthetic methods for diverse multinuclear complexes. The results described can be used to selectively connect mononuclear as well as multinuclear complexes with other metal complexes to construct valuable photofunctional compounds. Using the new synthetic methods, it was possible to selectively connect several types of metal complexes in a single step under relatively mild reaction conditions. This so-called building block approach utilizes various C-C coupling reactions between metal complexes with functional groups as active moieties. Owing to the large pi-conjugation systems, the multinuclear complexes synthesized using coupling reactions showed a strong absorption ability over a wide range of visible light and long emission lifetimes, which are ideal properties for photosensitizers and light absorbers. By combining these coupling methods with the newly developed hydrogenation reactions, the binding mode of the linkers in multinuclear complexes can be modified in order to tune the photophysical properties and photocatalytic ability. As such, the synthesized multinuclear complexes can be used for various purposes, e.g., as photocatalysts and photosensitizers, and in light-harvesting systems. The synthetic methods and strategies presented in this book diversify not only the structures but also functions of multinuclear complexes.

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