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Catalysis by Unique Metal Ion Structures in Solid Matrices: From Science to Application

Catalysis by Unique Metal Ion Structures in Solid Matrices: From Science to Application

Paperback

Series: NATO Science Series II: Mathematics, Physics and Chemistry, Book 13

Chemistry

ISBN10: 0792368754
ISBN13: 9780792368755
Publisher: Springer Nature
Published: Mar 31 2001
Pages: 332
Weight: 1.06
Height: 0.72 Width: 6.14 Depth: 9.21
Language: English
Atomically dispersed metal cations and small polyatomic cationic structures co-ordinated to the surface of porous matrices exhibit different properties from the same cationic species contained in a bulk oxide or supported on amorphous carriers. This subject is treated to an extensive review, showing how an understanding of it is essential to the development of a new generation of solid catalysts. There are also exciting opportunities to shape the catalytic properties of the transition metal cations in microporous and mesoporous matrices.
The book covers both theoretical and experimental aspects, including the distribution of framework Al atoms in Si-rich zeolites, distribution and siting of charge-exchanged metal cations, electronic, adsorptive and catalytic properties of metal cations, and correlation of metal cation structure and siting with catalytic activity.

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