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  • Open Daily: 10am - 10pm
    Alley-side Pickup: 10am - 7pm

    3038 Hennepin Ave Minneapolis, MN
    612-822-4611

Open Daily: 10am - 10pm | Alley-side Pickup: 10am - 7pm
3038 Hennepin Ave Minneapolis, MN
612-822-4611
The Anomeric Effect and Related Stereoelectronic Effects at Oxygen

The Anomeric Effect and Related Stereoelectronic Effects at Oxygen

Kirby, A. J.

Paperback

Series: Reactivity and Structure: Concepts in Organic Chemistry, Book 15

Chemistry

ISBN10: 3642686788
ISBN13: 9783642686788
Publisher: Springer Nature
Published: Mar 21 2012
Pages: 152
Weight: 0.60
Height: 0.35 Width: 6.69 Depth: 9.61
Language: English
The anomeric effect is a well-defined and much studied example of a deep- seated and very general effect in organic chemistry. It involves a fundamental interaction between the lone pair electrons of oxygen and the antibonding orbitals of adjacent bonds, which can control not only conformation but also reactivity in suitable systems. So the heart of this book is a consideration of the properties of non-bonding pairs of electrons, and the influence of orbital- orbital interactions on structure and reactivity. I have been lucky in recent months to be able to discuss various matters arising in this book with people who know more about them than I do. Parti- cularly Professors C. Altona, A. Eschenmoser, F. Hirshfeld, M. Lahav, R.A. McClelland, G.M. Sheldrick and A. Vos, and, nearer horne, I. Fleming, P.G. Jones, AJ. Stone (who helped with the rather theoretical Appendix) and I.H. Williams. I am also most grateful to Professors P. Deslongchamps, ID. Dunitz, D.G. Gorenstein, W.P. Jencks, G.A. Jeffrey, R.D. Lemieux and S. Wolfe, for very helpful correspondence, and information in advance of pUblication. I have covered the literature received in Cambridge up to early December 1981.

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